Can dried catnip be used against roaches?
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I haven’t heard that one. If you’re looking for a less toxic cockroach solution, you can try applying boric acid in a thin layer near roach-trafficked areas. This site is fairly informative about application and the benefits of using boric acid:
http://www.ca.uky.edu/entomology/entfacts/ef614.asp
I am not sure about the Catnip, but dryer sheets like bounce acts like a repellent for ants and those big roach looking water bugs. There is something in a dryer sheet that turns them away. Try putting one of these dryer sheets outside near some ants or other bugs and watch how they avoid going near it.